Preparation of soap |
SOAPS AND
DETERGENTS
Soaps –
preparation of soaps –
Detergents –
advantages and disadvantages.
REVIEW
You have
learnt the reasons for hardness of water.
Let us recall some of them.
·
Water which
readily produces lather with soap is called soft water and that which does not
readily produce lather is called hard water.
·
Hard water
contains dissolved sulphates, chlorides and bicarbonates of calcium and
magnesium.
·
The natural water
is generally impure.
·
The polar nature
of water makes it an excellent solvent.
INTRODUCTION
When water
is used for washing, it dissolves dirt; but some dirt will not dissolve in
water. Soaps and detergents help water to remove dirt. The rod detergent means
something which cleans. Soapnut powder has been inuse for about 3,000 years. In
India even now some still use soapnut powder as a natural soap to remove oily
substance. People have been using soap for a long time.
SOAPS
Metallic
salts prepared from natural fats are called soaps. Soap is a sodium salt or
potassium salt of long chain fatty acide that has clensing action in water.
Sodium stearate, sodium oliate and sodium plamitate are some examples of soaps.
Stearic
acid is a long chain fatty acid. Its formula is C17H35COOH.
This reacts with sodium hydroxide to give a compound called sodium stearate,
which has properties of soap.
Similarly,
sodium hydroxide reacts with oleic acid and plamitic acid forming sodium oleate
(C17H33COONa) and sodium palmitate C17H31
COONa) respectively.
Please note
!
Fatty acids
are organic compounds. The molecules of these compounds contain a carboxyl
group (-COOH). These molecules react with a trihydric alcohol called glycerol
to form a class of compounds called esters. Groundnut oil, coconut oil, palm
oil, caster oil, ginegely oil, animal fat etc are all esters of fatty acids.
Fats and fatty oils are called glyceryl esters or glycerides.
While
writing the formulae of inorganic csalts. It is the convention to write cation
first However cation js written at end in the case of organic salts. Consider
the following examples
Sodium
chloride - NaCL
Sodium
acetate - Ch3COONa
PRPARATION OF SOAP
Experiment
: Take about 30 ml of a vegetable oil in
a beaker. Add about 60 ml of 20% sodium hydroxide solution to it. Heat slowly
until the mixture boils. After 5-10 mimutes of boiling, add about 5g of sodium
chloride to separate soap from the solution. Cool the solution. Observe the
creamy layer of soap floating on the solution.
When a
mixture of a oil/fat and a strong solution of sodium hydroxide is boiled in an
iron tank, a sodium salt of the fatty acid and glycerol ane formed. The sodium
salt of the fatty acid thus formed is nothing but soap.
Preparation of soap Experiment. |
A Swedish
chemist, Carl Wihelm Scheel, discovered accidentally the process of preparation
of soap in 1783. He boiled olive oil with lead oxide and obtained a substance
which was sweet to taste. This substance is now known as glycerine.
Oil/fat +
Sodium hydroxide – soap + glycerol
Glycerol
Glycerol is
a sweet viscous liquid soluble in water. It is a byproduct of saponification
process. It is commonly called glycerine. Its formula is CH2OH.CHOH.CH2OH.
It is used in the manufacture of explosives, plastics. And pharmaceuticals. It
is also used to prevent freezing.
Soap thus
formed is separated with the help of sodium chloride. Addition of sodium
chloride reduces the solubility of soap considerable. Soap, being lighter,
flots like a cream on the solution. It is separated from the solution, suitable
chemicals of suitable colour and odour are added to it and cast into moulds.
When soap cools and solidifies, it is cut into desired shapes and packed.
Glycerol exists in dissolved state in the solution. It is separated by
distillation.
How does
soap clean ?
Soap cleans process |
Soap
dissolves in water. This is due to the contrasting properties of the ends of
the soap molecules. A soap molecule has a long hydrocarbon end (Ex:CH3(CH2)16)
and a short ionic end containing COONA+.
The non-ionic hydrocarbon end attaches to the dirt or grease to form structures
called ‘micelles’.
1.
water 2. soap
molecule 3. Dirt
In micelles
soap molecules are arranged radially. The end attached to water pulls out the
dirt from the fabric. This can be washed off with water.
DETERGENTS
The term
detergent is derived from a Latin word which means surface active. Synthetic
detergents are commonly known as detergents. Detergents are also called
soapless soaps. Detergents do not from insoluble ‘scum’ with magnesium and
calcium ions present in hard water. Therefore, detergents clean better than
soap even in hard water.
Detergents
are sodium salts of long chain benzene sulphonic acid or sodium salts of long
chain alkyl hydrogen sulphate. A detergent molecule consists of a large
hydrocarbon group that is non-ionic and a sulphonate (SO3- Na+)
or a sulphate (SO4-Na+) group that is ionic. Sodium
n-dodecyl benzene sulphonate and sodium dodecyl sulphate are two well-known
detergents.
Let us now
consider a method of making detergents. Long chain hydrocarbons obtained from
petroleum are treated with concentrated sulphuric acid. The organic acids
produced during this process are neutralized with sodium hydroxide. The sodium
salt obtained is a detergent.
ADVANTAGES OF
DETERGENTS OVER SOAPS
Detergents
have more advantages that soap. Therefore. Detergents are more widely used that
soap. Let as now turn our focus towards the advantages of detergents.
·
Detergents
cleanse well even in hard water. Soap is not so good for washing when water is
hard.
·
Detergents are
made from hydrocarbons obtained from petroleum. Soap is prepared from vegetable
oil or animals, fat that are usually edible. Detergents are not bio-degradable.
Soaps are biodegradable.
·
Detergents
cleanse well evening acidic medium. Soap does not cleanse well in such a
medium.
Detergents
have their disadvantages.
·
Detergents are
non bio-degradable. They pollute water and soil.
Points to
remember :
·
Metallic salts
prepared from natural fats are called soaps.
·
Sodium hydroxide,
fatty acid and sodium chloride are the raw materials used in the preparation of
soap.
·
Sodium oleate and
sodium palmitate are example for soap.
·
Detergents are
also called soapless soap.
·
Detergents
cleanse well even in hard water.
·
Detergents
cleanse well in acid medium.
·
Detergents
pollute water and soil.
·
The process of
preparing soap using sodium hydroxide or potassium hydroxide is called saponification.